What is carbon black pigment used for?

Chemical compound

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Chemical compound

Worker at carbon black plant,

Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid catalytic cracking tar, and ethylene cracking in a limited supply of air. Carbon black is a form of paracrystalline carbon that has a high surface-area-to-volume ratio, albeit lower than that of activated carbon. It is dissimilar to soot in its much higher surface-area-to-volume ratio and significantly lower (negligible and non-bioavailable) polycyclic aromatic hydrocarbon (PAH) content.

Carbon black is used as a colorant and reinforcing filler in tires and other rubber products; pigment and wear protection additive in plastics, paints, and ink pigment.[2] It is used in the EU as a food colorant when produced from vegetable matter (E153).

The current International Agency for Research on Cancer (IARC) evaluation is that, "Carbon black is possibly carcinogenic to humans (Group 2B)".[3] Short-term exposure to high concentrations of carbon black dust may produce discomfort to the upper respiratory tract through mechanical irritation.

Common uses

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The most common use (70%) of carbon black is as a pigment and reinforcing phase in automobile tires. Carbon black also helps conduct heat away from the tread and belt area of the tire, reducing thermal damage and increasing tire life. Its low cost makes it a common addition to cathodes and anodes and is considered a safe replacement to lithium metal in lithium-ion batteries.[4] About 20% of world production goes into belts, hoses, and other non-tire rubber goods. The remaining 10% use of carbon black comes from pigment in inks, coatings, and plastics, as well as being used as a conductive additive in lithium-ion batteries.[5]

Carbon black is added to polypropylene because it absorbs ultraviolet radiation, which otherwise causes the material to degrade. Carbon black particles are also employed in some radar absorbent materials, in photocopier and laser printer toner, and in other inks and paints. The high tinting strength and stability of carbon black has also provided use in coloring of resins and films.[6] Carbon black has been used in various applications for electronics. A good conductor of electricity, carbon black is used as a filler mixed in plastics, elastomer, films, adhesives, and paints.[6] It is used as an antistatic additive agent in automobile fuel caps and pipes.

Carbon black from vegetable origin is used as a food coloring, known in Europe as additive E153. It is approved for use as additive 153 (Carbon blacks or Vegetable carbon) in Australia and New Zealand[7] but has been banned in the US.[8] The color pigment carbon black has been widely used for many years in food and beverage packaging. It is used in multi-layer UHT milk bottles in the US, parts of Europe and Asia, and South Africa, and in items like microwavable meal trays and meat trays in New Zealand.

The Canadian Government's extensive review of carbon black in concluded that carbon black could continue to be used in products &#; including food packaging for consumers &#; in Canada. This was because "in most consumer products carbon black is bound in a matrix and unavailable for exposure, for example as a pigment in plastics and rubbers" and "it is proposed that carbon black is not entering the environment in a quantity or concentrations or under conditions that constitute or may constitute a danger in Canada to human life or health."[9]

Within Australasia, the color pigment carbon black in packaging must comply with the requirements of either the EU or US packaging regulations. If any colorant is used, it must meet European partial agreement AP(89)1.[10]

Total production was around 8,100,000 metric tons (8,900,000 short tons) in .[11] Global consumption of carbon black, estimated at 13.2 million metric tons, valued at US$13.7 billion, in , is expected to reach 13.9 million metric tons, valued at US$14.4 billion in .

While distinct from soot and similar particulates, carbon black can be used as a model compound for diesel soot to better understand how diesel soot behaves under various reaction conditions. Carbon black and diesel soot have some similar properties such as particle sizes, densities, and copolymer adsorption abilities that contribute to them having similar behaviours under various reactions such as oxidation experiments.[12][13][better source needed]

Global consumption is forecast to maintain a CAGR (compound annual growth rate) of 5.6% between and , reaching 19.2 million metric tons, valued at US$20.4 billion, by .[14]

Reinforcing carbon blacks

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The highest volume use of carbon black is as a reinforcing filler in rubber products, especially tires. While a pure gum vulcanization of styrene-butadiene has a tensile strength of no more than 2 MPa and negligible abrasion resistance, compounding it with 50% carbon black by weight improves its tensile strength and wear resistance as shown in the table below. It is used often in the aerospace industry in elastomers for aircraft vibration control components such as engine mounts.

Certain types of carbon black used in tires, plastics and paints Name Abbrev. ASTM
desig. Particle
Size
nm Tensile
strength
MPa Relative
laboratory
abrasion Relative
roadwear
abrasion Super Abrasion Furnace SAF N110 20&#;25 25.2 1.35 1.25 Intermediate SAF ISAF N220 24&#;33 23.1 1.25 1.15 High Abrasion Furnace HAF N330 28&#;36 22.4 1.00 1.00 Easy Processing Channel EPC N300 30&#;35 21.7 0.80 0.90 Fast Extruding Furnace FEF N550 39&#;55 18.2 0.64 0.72 High Modulus Furnace HMF N660 49&#;73 16.1 0.56 0.66 Semi-Reinforcing Furnace SRF N770 70&#;96 14.7 0.48 0.60 Fine Thermal FT N880 180&#;200 12.6 0.22 &#; Medium Thermal MT N990 250&#;350 9.8 0.18 &#;

Practically all rubber products where tensile and abrasion wear properties are important use carbon black, so they are black in color. Where physical properties are important but colors other than black are desired, such as white tennis shoes, precipitated or fumed silica has been substituted for carbon black. Silica-based fillers are also gaining market share in automotive tires because they provide better trade-off for fuel efficiency and wet handling due to a lower rolling loss. Traditionally silica fillers had worse abrasion wear properties, but the technology has gradually improved to a point where they can match carbon black abrasion performance.

Pigment

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Carbon black (Color Index International, PBK-7) is the name of a common black pigment, traditionally produced from charring organic materials such as wood or bone. It appears black because it reflects very little light in the visible part of the spectrum, with an albedo near zero. The actual albedo varies depending on the source material and method of production. It is known by a variety of names, each of which reflects a traditional method for producing carbon black:

• Ivory black was traditionally produced by charring ivory or bones (see bone char).
• Vine black was traditionally produced by charring desiccated grape vines and stems.
• Lamp black was traditionally produced by collecting soot from oil lamps.

All of these types of carbon black were used extensively as paint pigments since prehistoric times.[15] Rembrandt, Vermeer, Van Dyck, and more recently, Cézanne, Picasso and Manet[16] employed carbon black pigments in their paintings. A typical example is Manet's "Music in the Tuileries",[17] where the black dresses and the men's hats are painted in ivory black.[18]

Newer methods of producing carbon black have largely superseded these traditional sources.[citation needed] For artisanal purposes, carbon black produced by any means remains common.[6]

Surface and surface chemistry

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All carbon blacks have chemisorbed oxygen complexes (i.e., carboxylic, quinonic, lactonic, phenolic groups and others) on their surfaces to varying degrees depending on the conditions of manufacture.[19] These surface oxygen groups are collectively referred to as volatile content. It is also known to be a non-conductive material due to its volatile content.

The coatings and inks industries prefer grades of carbon black that are acid-oxidized. Acid is sprayed in high-temperature dryers during the manufacturing process to change the inherent surface chemistry of the black. The amount of chemically-bonded oxygen on the surface area of the black is increased to enhance performance characteristics.

Use in lithium-ion batteries

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The generic structure of carbon black.

Carbon black is a common conductive additive for lithium-ion batteries as the particles have small sizes and a large specific surface areas (SSA) which allow for the additive to be well distributed throughout the cathode or anode in addition to being cheap and long-lasting.[5][20] Unlike graphite, which is one of the other common materials used in chargeable batteries, carbon black consists of crystal lattices that are further apart and promotes Li+ intercalation because it allows more pathways for lithium storage.[20]

Carbon black has a low density that allows for a large volume of it to be dispersed so that its conductive effects are applied evenly throughout the battery.[21][22] Furthermore, its arrangement of randomly distributed graphite-like crystals improves battery stability because of the decrease in the potential barrier of lithium intercalation into graphite, which ultimately affects the performance of cathodes.[20]

While carbon black is lightweight and well dispersed throughout the battery and increases the conductive performance of batteries, it also contains oxygen containing hydrophilic functional groups that can cause side reactions to occur in the battery and lead to the decomposition of electrolyte. Graphitization (heating) of carbon black can thermally decompose the hydrophilic functional groups and thus increase the cycle life of the battery which maintains the conductive abilities of carbon black while mitigating the damage that can be caused to batteries by hydrophilic functional groups.

Half cells created with heavy graphitization, light graphitization, and no graphitization showed that the cell created with heavy graphitization had a stable cycle life of 320 cycles, the cell with light graphitization showed a stable cycle life of 200 cycles, and the cell with no graphitization showed a stable cycle life of 160 cycles.[5]

Safety

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Carcinogenicity

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Carbon black is considered possibly carcinogenic to humans and classified as a Group 2B carcinogen because there is sufficient evidence in experimental animals with inadequate evidence in human epidemiological studies.[3] The evidence of carcinogenicity in animal studies comes from two chronic inhalation studies and two intratracheal instillation studies in rats, which showed significantly elevated rates of lung cancer in exposed animals.[3] An inhalation study on mice did not show significantly elevated rates of lung cancer in exposed animals.[3] Epidemiologic data comes from three cohort studies of carbon black production workers. Two studies, from the United Kingdom and Germany, with over 1,000 workers in each study group showed elevated mortality from lung cancer.[3] A third study of over 5,000 carbon black workers in the United States did not show elevated mortality.[3] Newer findings of increased lung cancer mortality in an update from the UK study suggest that carbon black could be a late-stage carcinogen.[23][24] However, a more recent and larger study from Germany did not confirm this hypothesis.[25]

Occupational safety

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There are strict guidelines available and in place to ensure employees who manufacture carbon black are not at risk of inhaling unsafe doses of carbon black in its raw form.[26] Respiratory personal protective equipment is recommended to properly protect workers from inhalation of carbon black. The recommended type of respiratory protection varies depending on the concentration of carbon black used.[27]

People can be exposed to carbon black in the workplace by inhalation and contact with the skin or eyes. The Occupational Safety and Health Administration (OSHA) has set the legal limit (Permissible exposure limit) for carbon black exposure in the workplace at 3.5 mg/m3 over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a Recommended exposure limit (REL) of 3.5 mg/m3 over an 8-hour workday. At levels of  mg/m3, carbon black is immediately dangerous to life and health.[28]

See also

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References

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Further reading

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What is carbon black? A vital component in making many of the products we use every day stronger, deeper in color and longer lasting, carbon black in its pure form is a fine black powder, essentially composed of elemental carbon. It is produced by partial burning and pyrolysis of low-value oil residues at high temperatures under controlled process conditions.

Carbon black is mainly used to strengthen rubber in tires, but can also act as a pigment, UV stabilizer, and conductive or insulating agent in a variety of rubber, plastic, ink and coating applications. Apart from tires, other everyday uses of carbon black include hoses, conveyor belts, plastics, printing inks and automotive coatings.

The fundamental properties of carbon black determine application performance. These include:

• Particle Size
• Structure
• Porosity
• Surface Chemistry or Surface Activity
• Physical Form

PARTICLE SIZE

Measured by electron microscopy, this is the fundamental property that has a significant effect on rubber properties, as well as color properties for specialty carbon blacks.

For specialty carbon blacks, smaller particle diameter gives rise to higher surface area and tinting strength. High surface area is usually associated with greater jetness, higher conductivity, improved weatherability, and higher viscosity, but requires increased dispersion energy.

For rubber, finer particles lead to increased reinforcement, increased abrasion resistance, and improved tensile strength. To disperse finer particles size, however, requires increased mixing time and energy. Typical particle sizes range from around 8 nanometers to 100 nanometers for furnace blacks. Surface area is utilized in the industry as an indicator of the fineness level of the carbon black and, therefore, of the particle size.

STRUCTURE

This is a measure of the three-dimensional fusion of carbon black particles to form aggregates, which may contain a large number of particles. The shape and degree of branching of the aggregates is referred to as structure.

Highly structured carbon blacks provide higher viscosity, greater electrical conductivity and easier dispersion for specialty carbon blacks. Measures of aggregate structure may be obtained from shape distributions from EM analysis, oil absorption (OAN) or void volume analysis.

The structure level of a carbon black ultimately determines its effects on several important in-rubber properties. Increasing carbon black structure increases modulus, hardness, electrical conductivity, and improves dispersibility of carbon black, but increases compound viscosity.

POROSITY

This is a fundamental property of carbon black that can be controlled during the production process. It can affect the measurement of surface area providing a total surface area (NSA) larger than the external value (STSA).

Conductive specialty carbon blacks tend to have a high degree of porosity, while an increase in porosity also allows a rubber compounder to increase carbon black loading while maintaining compound specific gravity. This leads to an increase in compound modulus and electrical conductivity for a fixed loading.

SURFACE CHEMISTRY OR SURFACE ACTIVITY

This is a function of the manufacturing process and the heat history of a carbon black and generally refers to the oxygen-containing groups present on a carbon black&#;s surface.

For specialty carbon blacks, oxidized surfaces improve pigment wetting, dispersion, rheology, and overall performance in selected systems. In other cases, oxidation increases electrical resistivity and makes carbon blacks more hydrophilic. The extent of surface oxidation is measured by determining the quantity of the &#;volatile&#; component on the carbon black. High volatile levels are associated with low pH.

While difficult to measure directly for rubber, surface chemistry manifests itself through its effects on such in-rubber properties as abrasion resistance, tensile strength, hysteresis, and modulus. The effect of surface activity on cure characteristics will depend strongly on the cure system in use.

PHYSICAL FORM

This is important in matching a carbon black to the equipment by which it is to be dispersed. The physical form (beads or powder) can affect the handling and mixing characteristics.

The ultimate degree of dispersion is also a function of the mixing procedures and equipment used. Powdered carbon blacks are recommended in low-shear dispersers and on three-roll mills. Beaded carbon blacks are recommended for shot mills, ball mills, and other high energy equipment. Beading provides lower dusting, bulk handling capabilities, and higher bulk densities, while powdered carbon blacks offer improved dispersibility.

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